Releases of micropollutants from building surface materials into rainwater and snowmelt induced runoff.

Building surface materials, exposed to wash-off by rainwater or snowmelt, are recognised as one of the significant urban diffuse pollution sources contributing to the impairment of stormwater quality. The pollution conveyed by roof runoff originates from two potential sources, migration of surface material constituents, or wash-off of pollutants deposited on the surface by atmospheric deposition. This study investigated the releases of metals and several groups of contaminants of emerging concern: alkylphenols, alkylphenol ethoxylates, and phthalates, from commercially available materials, which are commonly used on buildings and structure surfaces in the urban environment. The materials tested included the following: metal sheets of stainless steel, copper, zinc, galvanised steel, corten steel, corrugated and coated steel, coated zinc; and bitumen-based roofing felt and shingles, as well as polyvinyl chloride (PVC) from two manufacturers. The stainless steel was considered a control material serving to estimate pollutant contributions deposited on the pilot panels from the surrounding environment. Moreover, this study presents novel data on roof snowmelt induced runoff quality, not reported in the previous literature. The experimental setup consisted of 2-m2 rectangular panels mounted in triplicates of each material and placed in an open-air setting on the campus of Luleå University of Technology, Sweden. Runoff leaving the gently sloping material panels was collected during 11 rain and three snowmelt driven runoff events occurring over a five-year period. The results showed that, in general, the micropollutant concentrations and loads were lower in snowmelt than rain induced runoff, and no decreasing trend was detected in the releases of phthalates or metals during the study period. Moreover, on a yearly basis, copper sheets were estimated to release 0.6 g/m2 Cu to runoff, zinc and galvanised sheets 1.3 and 0.7 g/m2 Zn, respectively, and, PVC sheets were estimated to release up to 78 mg/m2 of diisononyl phthalate (DINP).

Abundance, distribution, and composition of microplastics in the filter media of nine aged stormwater bioretention systems.

Bioretention systems are designed for quality treatment of stormwater. Particulate contaminants are commonly treated efficiently and accumulate mainly in the surface layer of the bioretention filter material. However, concerns exist that microplastic particles may not show equal accumulation behavior as other sediment particles. So far only two field and two laboratory studies are available on the fate of microplastics in few relatively newly built bioretention systems. Therefore, this study investigated the abundance and distribution of microplastics in nine 7-12 years old stormwater bioretention systems. It was found that microplastics generally accumulate on the surface of bioretention systems. Microplastic median particle concentrations decreased significantly from the surface layer (0-5 cm) of the filter material to the 10-15 cm depth layer from 448 to 136 particles/100 g, respectively. The distance to the inlet did not significantly affect the surface accumulation of microplastic particles, suggesting modest spatial variability in microplastics accumulation in older bioretention systems. Further, this study investigated the polymer composition in bioretention systems. It was shown that PP, EVA, PS and EPDM rubber are the most abundant polymer types in bioretention systems. Also, it was found that large percentages of microplastic particles are black particles (median percentage of black particles: 39%) which were found in 28 of the 33 investigated samples. This underlines the importance of including black particles in microplastic studies on stormwater, which has been overlooked in most previous studies.

Synthetic stormwater for laboratory testing of filter materials.

Synthetic stormwater was tested to determine the ageing effects on dissolved metal concentrations and used in a column experiment to determine efficiency of four different filter materials (milkweed, bark, peat, polypropylene) in removing total and dissolved metals. Synthetic stormwater was created by adding metal salts, oil and collected stormwater sediment to tap water. Two ageing experiments were performed to determine the change of synthetic stormwater quality over time. One experiment lasted for 11 days and another focused on rapid concentration changes one day after preparation. The one-day ageing experiment showed rapid decrease in dissolved concentration of certain metals, specifically Cu. To consider this change, correction coefficients for each metal were developed and used to estimate the average dissolved metal concentration in the synthetic stormwater during the experiment to determine filter treatment efficiency. During the 11-day experiment on metal concentrations, no noticeable quality changes were observed for at least six days after the preparation of synthetic stormwater. Furthermore, a column experiment was run with duplicate filter columns. Inflow and outflow samples were analysed for total and dissolved metals, turbidity, particle size distribution, and pH. High removal of total metal concentrations was noticed in all tested filter media (58-94%). Dissolved metal concentration removal varied among different filter media. In general, columns with bark and peat media were able to treat dissolved metals better than polypropylene and milkweed. The level of treatment of dissolved metals between the different filter media columns were bark > peat > milkweed > polypropylene.

Contamination of Urban Stormwater Pond Sediments: A Study of 259 Legacy and Contemporary Organic Substances.

Stormwater ponds improve water quality by facilitating the sedimentation of particles and particulate contaminants from urban runoff. Over time, this function entails the accumulation of contaminated sediments, which must be removed periodically to maintain a pond's hydraulic and treatment capacity. In this study, sediments from 17 stormwater sedimentation facilities from four Swedish municipalities were analyzed for 259 organic substances likely to be found in the urban environment. A total of 92 substances were detected in at least one sample, while as many as 52 substances were detected in a single sample. A typical profile of urban contamination was identified, including polychlorinated biphenyls, polycyclic aromatic hydrocarbons, organotins, aliphatic hydrocarbons, phthalates, aldehydes, polybrominated diphenyl ethers, perfluorinated substances, and alkylphenols. However, levels of contamination varied greatly between ponds, influenced heavily by the dilution of urban pollutants and wear particles from other sources of particles such as eroded soil, sand, or natural organic matter. For 22 of 32 samples, the observed concentrations of at least one organic substance exceeded the regulatory threshold values derived from toxicity data for both sediment and soil.

Removal of metals and hydrocarbons from stormwater using coagulation and flocculation.

As the understanding of how stormwater pollutants are fractioned and need for mitigation has increased, so has the investigation into more advanced treatment techniques. The present study investigated the treatment efficiency of coagulation/flocculation and sedimentation in semi-synthetic stormwater. Five coagulants were evaluated in terms of reducing particle content, organic carbon, total and dissolved metals, hydrocarbon oil index, and polycyclic aromatic hydrocarbons (PAHs). Changes in the resulting particle size distribution as a consequence of the coagulation treatment were also investigated. The pollutants in the semi-synthetic stormwater were predominantly in the particulate phase. The medium and longer chained hydrocarbons dominated the hydrocarbon oil index, while medium to high molecular weight PAHs were most abundant. Iron chloride was the only coagulant that affected particle size distribution post-treatment, shifting the distribution toward larger particles. In terms of total metal removal, the performance of the coagulants was similar, with over 90% removal on average. Concentration of zdissolved copper, one of the metals found in the dissolved phase, was reduced by 40% via coagulation treatment. The iron chloride coagulant increased dissolved Zn, a change attributed to a considerable drop in pH resulting in higher ion mobility. Similarly, the reduction in organic content (total organic carbon, oil, and PAHs) was over 90% for most coagulants.

Building surface materials as sources of micropollutants in building runoff: A pilot study.

Control of diffuse pollution is critical for achieving good surface water quality status. In this context, pollutant contributions from building materials have received increased attention in recent decades. This study examined the releases of metals, nonylphenols and phthalates from ten common building surface materials (installed in triplicates) into rainwater runoff from six rain events. The highest releases of metals were from copper and zinc sheets (average concentrations of 3090 µg/L Cu and 7770 µg/L Zn respectively), while other metal materials, e.g., Corten weathering steel, exhibited lower releases. PVC roofing released high concentrations of nonylphenols and phthalates (average concentrations of up to 26 µg/L nonylphenols and 455 µg/L Diisononyl phthalate, DINP) which have not been investigated in the earlier studies. Pollutant releases varied between events, likely because of weather conditions and rainfall characteristics. Study findings should be valuable for environmentally responsible applications of the existing building materials and the development of new ones, as well as the investigations and risk assessment of specific pollutants in stormwater.

Effect of temperature on the performance of laboratory-scale phosphorus-removing filter beds in on-site wastewater treatment.

P-sorbing filter beds appear to be viable options for treating wastewater to reduce P discharges and recover this non-renewable resource. However, greater knowledge of filters' responses to temperature variations is required to assess their likely performance in full-scale applications and facilitate the transfer of laboratory results to the field. Thus, in the present study two filter materials (Top16 and Polonite) were characterized physicochemically and effects of temperature on their performance were investigated under controlled laboratory conditions. Using a 2(2) factorial design and secondary wastewater eight filter columns were tested at temperatures of 4.3°C and 16.5°C. Temperature significantly (α=0.05) and strongly affected the P binding capacity of both materials, as it was 1.2- and 1.5-fold higher at 16.5°C than at 4.3°C for Top16 and Polonite, respectively. This is probably due to the enhanced precipitation of calcium phosphates at higher temperature. Observed reductions in total organic carbon content in the wastewater were also positively correlated with temperature, while the pH and reduction of dissolved organic carbon remained unaffected. The physicochemical analyses indicated that several calcium phases dissolved from the filter materials, primarily gypsum and bassanite from Top16 and Portlandite from Polonite. No clear evidence of any crystalline calcium phosphates was observed in the used materials. The results clearly show that temperature strongly influences the retention of P in filters and its effects should be carefully considered before using candidate filters in full-scale applications.

Measuring solids concentrations in urban stormwater and snowmelt: a new operational procedure.

A comparative study of five methods measuring suspended sediment or solid concentrations in water-sediment mixtures indicated that, depending on the method used, broadly varying results can be obtained. For water-sediment mixtures containing sand size particles, the standard TSS method produced negatively biased results, accounting for 0 to 90% of the present solids; the negative bias directly depended on the magnitude of the sand fraction in the water-sediment mixture. The main reason for the differences between the TSS and the rest of the methods laid in the handling of samples; in the former methods, whole samples were analysed, whereas the TSS analysis was performed on sub-samples withdrawn from the water sample, the withdrawal process tending to exclude large particles. The methods using whole water-solid samples, rather than aliquots withdrawn from such samples, produced accurate estimates of solid concentrations, with a fairly good precision. Two whole-sample methods were studied in detail, a slightly modified standard SSC-B method and the newly proposed operational procedure referred to as the Multiple Filter Procedure (MFP), using three filters arranged in a series with decreasing pore sizes (25, 1.6 and 0.45 µm). Both methods assessed accurately concentrations of solids in a broad range of concentrations (200-8000 mg L(-1)) and particle sizes (0.063-4.0 mm). The newly introduced MFP was in good agreement with the SSC procedure, the differences between the two procedures not exceeding the standard bias defined for the SSC-B method. The precision of both SSC and MFP was generally better than ±10%. Consequently, these methods should be used when the total mass of transported solids is of interest.